Coordinatively unsaturated metal centers may interact with a C-H bond of a coordinated ligand and then undergo C-H bond activation or fission to form metallacycles

Arenes are aromatic compounds which can act These complexes with three simple ligands are called as π-electron donors. Organometallic complexes with such ligands are commonly known as arene complexes, arene metal complexes ...

Free radicals can be defined as chemical species (atom, molecule or ion) which have a single unpaired valence electron.

Diels-Alder (D-A) reaction is a (4π+2π) cycloaddition reaction. It is used to generate six-membered rings by combining two π-systems. The key components of this reaction are a conjugated diene (an alkene with two π-bonds) ...

n an insertion reaction, Y gets transferred on to a ligand (AB).

Polymers play an important role in our day-to-day life. In Greek, poly means “many” and mer means “parts”. Polysaccharides, proteins and nucleic acids are the main bio-polymers/macromolecules. A large number of industries ...

Isomers (compounds with the same chemical formula) can be broadly classified into (i) stereoisomers (e.g. geometrical and optical) with the same connectivity but having different spatial arrangements and (ii) structural ...

Carbon monoxide is a good π-acceptor and the M-C bond in metal carbonyls [M(CO)n ] has a significant π character. Thus, the M-C bond is strengthened and the carbon oxygen bond is weakened with the increase in back bonding.

Metathesis of simple salts is a double replacement reaction as shown below. AX + BY → AY + BX In Greek, “Metathesis” is known as the change of position or transposition. Olefin metathesis (OM) is the catalytic scission ...

Organic chemistry is basically the study of synthesis, reactions, properties, and structures of carbon-containing compounds. Organic reactions can be classified into four main types: addition, elimination (E), substitution, ...